PHYS 203 Thermal Physics I – Course Content

Chronological table of course content. Readings, deadlines and links to files.

2023-2024 school year (2023W)

This will be updated (almost) daily as we go through the course. Please check here first if you need anything.

  • Future information (except for test dates and deadlines) is subject to change
  • Weekly Practice assignments are due every Tuesday. They will be online, in WeBWorK (WeBWorK basic info for those who are not familiar with it), accessed from the Canvas page.
  • Problem Sets will be posted at least a week in advance. Solutions will be posted after the due date.
  • Available before class:
    • Worksheets are generally posted the evening before class. You may download a PDF version of the worksheet to work on in class if you prefer to work on a tablet or iPad.
    • Lecture slides will be posted before the lecture when applicable.
  • Worksheet solutions and lecture notes (with clicker question answers) are posted after the worksheet is completed in class.

Date 
(mo/day)
Deadlines, tests and reminders In-class topics and materialsTextbook readingsThings to do after class
Lecture
1
Tue
01/09
  





Course organization and syllabus
What is Thermal Physics?

Binomial coefficient distribution (worksheet)
Probability distribution of a large number of independent random variables: the central limit theorem

Intro slides Lecture 1
Worksheet 1: Binomial coefficients
Jupyter file: the coin toss experiment
Lecture 1 slides, worksheet discussion
Lecture 1 slides, annotated

Watch: The Galton Board YouTube video: another way to think about binomial coefficients
Schroeder 2.1 Read the course Syllabus

Another great YouTube video(by 3Blue1Brown) on Binomial distributions. The details relevant to us start at 5:40 if you want to skip ahead. 

Finally, if you are looking for a very basic intro to probability concepts, you can try chapters 1 and 3 from this online textbook (high school level) available from wikibooks.
Lecture
2
Thu
01/11
  


Finish Worksheet 1
Worksheet 1.5
Interactions: atoms moving between containers; energy moving between atoms

Lecture 2 notes, including slides and clicker questions
Lecture 2 slides, annotated 
Lecture 2 asynchronous recording

Worksheet 1 solutions: Jupyter code and output with some extra explanations and summary slides with answers and some more explanations; Solutions to the optional page of WS1. 

Solutions to worksheet 1.5.
We are covering this material in different order than the book. Don’t worry if the details don’t make sense to you yet, we will get to them. 

Schroeder 2.3 talks conceptually about the same things as the lecture, but uses a different example (the Einstein solid, section 2.2) that we have not covered yet.

You can read 2.3 for review of the concepts, or 2.2 and 2.3 together to get a more detailed view.
Work on the first Weekly Practice on WeBWorK (opens a new tab; you must be logged into Canvas to have this link take you to your Phys 203 WebWork). 

There are also “Orientation” and “Assignment 0” WebWork question sets there; these are just for optional practice, if you’re not used to using WebWork.  
Lecture
3
Tue
01/16


Weekly Practice 1 is due before class (9am). Thermal equilibrium
Thermodynamic limit
Macrostates, microstate, multiplicity
clicker questions and answers
Lecture 3 slides
Lecture 3 slides, annotated
Schroeder 2.1-2.3, for definitions mostly  
Weekly Practice 1 Solutions
Lecture
4
Thu
01/18
  


Temperature and beta
Probabilities and the Boltzmann factor
Partition function
Average energy 
Microscopic model of pressure

Lecture 4 slides
Lecture 4 slides, annnotated
Lecture 4 zoom recording (including after-class questions)
Schroeder 6.1, 6.2 (pages 229-230 only) ๐Ÿ™‚Friday, Jan 19 is the last day to withdraw from a course without a W standing. To withdraw from the course after Jan 19, contact Faculty of Science advising office.
Lecture
5
Tue
01/23
 




Weekly Practice 2 is due before class (9am).Ideal gas law (derivation)
Thermodynamics and functions of state 
Functional definition of temperature and a gas thermometer
Equipartition theorem

Lecture 5 slides
Lecture 5 slides, annotated
Lecture 5 zoom recording
Schroeder 1.1, 1.2, 6.3
Note on Schroeder’s approach vs our approach:
Since we were able to include the result of section 6.3 (average energy of a free, non-relativistic particle, equation (6.40)), we were able to derive the ideal gas law, rather than assume it the way the book does on page 12.
Schroeder 1.3, 1.4, 1.5 (up to page 22)
Weekly Practice 2 Solutions
Lecture
6
Thu
01/25
 

 
Practice Test 1 is available*** start of material for test 2***
More on the equipartition theorem (details and clicker questions from last lecture notes)
Work
Ideal gas heat and work:
Worksheet 2, parts 1 and 2 
Lecture 6 slides
Lecture 6 slides, annotated
Ideal gas heat and work:
Worksheet 2, parts 1 and 2 contd.
Schroeder 1.4, 1.5, 1.6Start working on
Problem Set 1
Lecture
7
Tue
01/30





Weekly Practice 3 is due before class (9am). Worksheet 2 solutions probs 1,2
*** end of material for test 1***
Heat capacity: first look, ideal gas only 
Finish WS2: part 3 work for an adiabatic curve
How a car engine works
Lecture 7 slides
Lecture 7 slides, annotated
Worksheet 3-4
Schroeder 4.1 (up to and including equation (4.1) + figures 4.1, 4.2 and 4.3) Weekly Practice 3 Solutions
Practice Test 1 answers
Lecture
8
Thu
02/01







Heat engines basic concept: efficiency 
Adiabatic transformations,
Heat engines: The Otto cycle
Heat capacities (in general) and latent heat
Worksheet 3
Heat engine example: Carnot cycle with ideal gas
Lecture 8 slides
Lecture 8 slides, annotated
Solutions to worksheet 3
Schroeder 4.3 (section on internal combustion engines only)Test 1 (evening 6pm-7pm, Hebb 100 (60 minutes)
It will cover lectures 1-7, together with appropriate sections from Schroeder as listed above, Worksheets 1-2 and Weekly Practice assignments 1-3.

Test 1 solutions
Midterm 1 reflection assignment
Optional reflection assignment for those with > 95%
Lecture
9
Tue
02/06


  






Weekly Practice 4 is due before class (9am).Intensive vs extensive quantities
A bit of a review: microstates, macrostates, fundamental assumption of Statistical Mechanics, the Law of Increase of Multiplicity, thermodynamic limit, beta and temperature
Entropy and the Second law of thermodynamics
Entropy and missing information
Lecture 9 slides
Lecture 9 slides, annotated

Schroeder 2.3 
Schroeder 2.4 (page 60 only) 
Schroeder 2.6 (up to page 77)
Schroeder 3.1
Schroeder 3.2 (section on The Macroscopic View of Entropy only)
Schroeder: Extensive end Intensive Quantities, pg 163-164
Weekly Practice 4 Solutions
Lecture
10
Thu
02/08
Problem Set 1 is due at 4pm.Connection between entropy and heat capacities
Reversible and irreversible processes, examples
Pressure as a derivative of internal energy
The (fundamental) thermodynamic identity
Lecture 10 slides
Lecture 10 slides, annotated
Schroeder 3.4
Schroeder 2.6 (reversible and irreversible processes)
Problem set 1 Solutions
Lecture
11
Tue
02/13
  


Weekly Practice 5 is due before class (9am).Entropy of the ideal gas
The Sackur-Tetrode equation
Mixing and entropy, entropy of mixing, identical particles
Lecture 11 slides
Lecture 11 slides, annotated

Schroeder 2.6 (entropy of an ideal gas) Schroeder 2.4 (pg 60-62)
Schroeder Fig 2.10 and the second sentence underneath
Schroeder 2.6 (entropy of mixing)

+ Schroeder 2.5 (section of Multiplicity is covered on the Worksheet, section on Interacting gases is similar in spirit to PS1, Q3 and PS2, Q4)
Weekly Practice 5 Solutions
Lecture
12
Thu
02/15
  


Practice Test 2 available over midterm break Mixing and entropy, entropy of mixing, identical particles (contd.)
Approximations, Stirling’s Approximation
Multiplicity of the ideal gas
The paramagnet in microcannonical ensemble, Worksheet 5 (part 1, paramagnet) 
Worksheet 5 (part 2, Einstein solid)
Solutions to Worksheet 5
Lecture 12 slides
Lecture 12 slides, annotated
*** end of material for test 2***
Schroeder 2.6 (entropy of mixing)
Schroeder 2.1
Schroeder 3.3
Schroeder 2.2
(WP 6 is included in Test 2 material)
Start working on Problem Set 2
(Feb 19-23)MID TERM BREAK
Practice Test 2
Monday Feb 19 is Family Day and UBC is closed.
Lecture
13
Tue
02/27



Weekly Practice 6 is due before class (9am).
Brief review of the material so far (test 2 concept review)

*** start of material for test 3***
Helmholtz free energy F: introduction
Enthalpy H; introduction
Lecture 13 slides
Lecture 13 slides, annotated
Schroeder 2.4 (pages 63-66: the book computes the multiplicity of the Einstein solid in the high temperature limit only, which makes the Stirling approximation harder to use; section on sharpness is similar in spirit to PS1, Q3 and PS2, Q4)
Schroeder 1.6 (enthalpy)
Schroeder 5.1 (up to page 155)
Weekly Practice 6 Solutions
Solutions to Practice Test 2
Lecture
14
Thu
02/29







Practice material is posted here and on Canvas 

Problem Set 2 is due Monday at 11:59pm.
Enthalpy H and Gibbs free energy G
Free energy as available work
Chemical reactions and batteries (as applications)

Lecture 14 slides
Lecture 14 slides, annotated





Test 2, evening 6pm-7pm, Chem B150 (60 minutes)
It will cover lectures 6-12 (the first half of lecture 13 is a useful review), together with appropriate sections from Schroeder as listed above, worksheets 3 and 5, and Weekly Practice assignments 4-6.
Bring your formula sheet!
Friday, Mar 1 (tomorrow) is the last day to withdraw from a course (with a W standing).
Lecture
15
Tue
03/05



Weekly Practice 7 is due before class starts (9am)Thermodynamic identities
Maxwell relations
Free energy wants to be minimized
Pressure from free energy 
Chemical potential and diffusive equilibrium
Thermodynamic identities with change in number of particles
Gibbs free energy and chemical potential
Worksheet 6
Worksheet 6, solns
Lecture 15 slides
Lecture 15 slides, annotated
Schroeder 5.1 (Thermodynamic Identities)
Schroeder 5.2 
Schroeder 3.5 (for chemical potential)
If you want to know more about the mathematics of Legendre transform, check out this article

Table of thermo numbers

Weekly Practice 7 Solutions

Problem set 2 solutions
Lecture
16
Thu
03/07
  
Phase transitions and phase diagrams
Phase transitions and Gibbs free energy
Clausius-Clapeyron relation 
Worksheet 7
Worksheet 7, solns
Lecture 16 slides
Lecture 16 slides, annotated
Schroeder 5.3 (pg 166-169, Clausius-Clapeyron)Test 2 solutions
Reflection assignment for Exam 2 (due Thu 03/14 11:59pm).
Lecture
17
Tue
03/12



Weekly Practice 8 is due before class starts (9am) Example: boiling water (worksheet 8)
More on phase transitions: graphite and diamond
nucleation and boiling (optional)
superheated and supercooled water (optional)
Worksheet 8
Lecture 17 slides
Lecture 17 slides, annotated

Schroeder 5.3 (except for van der Waals model) 

Water behaving weirdly:
Behaviour of water at its triple point: youtube video 
Supercooled water: youtube video Superheated water: youtube video 
One more phase diagram video, this time with nitrogen and its triple point: youtube video. Finally, dry ice (CO2) at its critical point: youtube video.
Weekly Practice 8 Solutions
Lecture
18
Thu
03/14
 


Vapour equation, vapour partial pressure and humidity, dew point
Heat engines: the general set-up and theory
Heat engines on a T-S diagram (not in the book!)

Lecture 18 slides
Lecture 18 slides, annotated
Worksheet 8 solutions
Schroeder 4.1, 4.2 
Problem Set 3 (HW3)
Problem Set 3 solutions
Lecture
19
Tue
03/19





Weekly Practice 9 is due before class starts (9am)  Heat engines on a T-S diagram (not in the book!)
Refrigerators and the COP
Real refrigerators and throttling (Joule-Thomson effect) 
COP of a real refrigerator
The steam engine

Lecture 19 slides
Lecture 19 notes
Schroeder 4.3 (except for steam engine)
Schroeder 4.4
Weekly Practice 9 Solutions
Lecture
20
Thu
03/21



The steam engine
(Worksheet 9)
Worksheet 9 solutions
*** end of material for test 3***

Back to Stat Mech: chapters 6 and 7  
Review of canonical approach to stat mech from the beginning of course. Boltzmann factor and probabilities
Partition function
Spectrum, multiplicities
Average energies (magic formula)

Lecture 20 slides
Lecture 20 slides, annotated
Schroeder 4.3 (steam engine) Schroeder 6.1
Schroeder 6.2 (without paramagnetism or rotation of diatomic molecules sections)
Schroeder 6.5
Practice Midterm 3
Practice Midterm 3, solutions

Weekly Practice 10 Solutions
Lecture
21
Tue
03/26


Weekly Practice 10 is due before class (9am)  
Partition function and (Helmholtz) free energy.
Average energy at fixed temperature (canonical ensemble), example: paramagnetism.
Partition function of composite systems
Worksheet 10
Worksheet 10 solutions

(distinguishable particles).
Continuous random variables and the probability density.
Proof of the equipartition theorem (again)
Lecture 21 slides
Lecture 21 slides, annotated with recording
Schroeder 6.2 (without rotation of diatomic molecules section)
Schroeder 6.3
Schroeder 6.4

Lecture
22
Thu
03/28
Speed distribution for a particle in one dimension
Speed distribution for a particle in three dimensions (Maxwell Speed Distribution)
Worksheet 11
Worksheet 11, solutions
Partition functions of distinguishable vs indistinguishable particles
Indistinguishable particles slide deck
Lecture 22 slides
Lecture 22 slides, annotated with recording
Ideal Gas in the canonical ensemble intro
Worksheet 12
Schroeder 6.6, 6.7 


Plots of the Maxwell distribution (useful for Weekly Practice 11) 

Test 3, evening 6:30pm-7:30pm, Hebb 100 (60 minutes)
It will cover lectures 13-20, together with the appropriate sections from Schroeder as listed above, worksheets 6-9, and Weekly Practice assignments 7-10.
The Practice exam is available above and on Canvas.

(UBC will be closed Friday March 29 and Monday April 1 for Easter long weekend.)
Lecture
23
Tue
04/02
Ideal Gas in the canonical ensemble
Worksheet 12
Worksheet 12, solutions
Partition function of a dilute composite system of N indistinguishable particles
The partition function and thermodynamics of the ideal gas
More on indistinguishable particles

Lecture 23 slides
Lecture 23 slides, annotated
Schroeder 6.6, 6.7 

(The textbook does a fully quantum mechanical treatment of the ideal gas in equations (6.75)-(6.79), before changing the sum to an integral which in effect takes the classical limit.)
Start working on Problem Set 4 (HW4)
Problem Set 4 solutions



Lecture
24
Thu
04/04
Weekly Practice 11 due before class starts (9am) Bosons and fermions
The Gibbs factor and the grand partition function

Lecture 24 slides
Lecture 24 slides, annotated
The Fermi-Dirac and Bose-Einstein distributions
Worksheet 13
Worksheet 13 solutions
Schroeder 7.1, 7.2
Schroeder 7.4 
Schroeder 7.3 (selected)
Weekly Practice 11 Solutions
Lecture
25
Tue
04/09
Density of states
Quantum gases (applications of FD and BE distributions)
Blackbody radiation

Lecture 25 slides
Lecture 25 slides, annotated
Worksheet 14 (material to study, but will not be graded)
Worksheet 14 solutions
Schroeder 7.4 
Schroeder 7.3 (selected)
Test 3 solutions
Reflection assignment for Exam 3
(due Tues 04/16 5:00pm).
Lecture
26
Thu
04/11
Weekly Practice 12 due before class starts (9am) 
Problem Set 3 due 11:59pm
Special topics (for fun): Black holes
Course evaluations
Lecture 26 slides
Lecture 26 slides, annotated
Weekly Practice 12 Solutions
Today, Thu April 11, is the last class ๐Ÿ™‚

Please submit your SEI reports: we need 75% response for 2pts on the final!
Exam period is April 16-27 inclusive, including Saturdays and Sundays. 
Final
Exam


April 24, 2024
Time: 3:30pm
Duration: 2 hours, 50 min.
Location: Biol 1000
Format: Similar to the Tests, but more multiple choice
Practice material to study for the Final
Worksheet 14 — problems and solutions after Test 3, for practice
Formula sheet for Final Exam (final version)
Final Exam cover sheets
Review session on Apr 18